英语翻译Thereforedissociative adsorptionof hydrogen is reduced,and hence the chance to have directsynthesis.19,28,31-33 Hydrogen is more likely to react with theoxygen present on the Pd2+ surface than with the inner part ofthe Pd cluster,with the

英语翻译Thereforedissociative adsorptionof hydrogen is reduced,and hence the chance to have directsynthesis.19,28,31-33 Hydrogen is more likely to react with theoxygen present on the Pd2+ surface than with the inner part ofthe Pd cluster,with the
英语翻译
Thereforedissociative adsorption
of hydrogen is reduced,and hence the chance to have direct
synthesis.19,28,31-33 Hydrogen is more likely to react with the
oxygen present on the Pd2+ surface than with the inner part of
the Pd cluster,with the condition mentioned above16,17,19,20,33,35
(i.e.,an acidic solution or the presence of halides).When contact
time between liquid and solid phases is longer,all the reactions
occur,adding further H2O2 degradation paths.For intermediate
gas and liquid flow rates,production rate is higher and selectivity
achieves very interesting values.Gas solubilization in the liquid
phase plays a key role; it can be modified by using solvent that
selectively increases H2 solubility,34 but also the pressure and
the ratio between gas and liquid flow rates can affect the
concentration of H2 and O2 in the liquid phase.
These observations allow concluding that operative condition
in the TBR may help in controlling the reaction network,in
addition to suitable catalysts,linking the catalyst and the reactor
design and operation.It has been proved that operative condi-
tions play a major role in driving the reactions toward high
selectivity for hydrogen peroxide.The results suggest that
reactor design and operation may be crucial to improve
productivity and selectivity in H2O2 synthesis,together with
developing better catalysts.

英语翻译Thereforedissociative adsorptionof hydrogen is reduced,and hence the chance to have directsynthesis.19,28,31-33 Hydrogen is more likely to react with theoxygen present on the Pd2+ surface than with the inner part ofthe Pd cluster,with the
thereforedissociative吸附
of hydrogen is reduced, and hence the chance to have direct
氢是降低的,因此有机会直接
synthesis.19,28,31-33 Hydrogen is more likely to react with the
合成.19,28,31-33氢更容易与反应
oxygen present on the Pd2+ surface than with the inner part of
氧在Pd2 +的表面比内部
the Pd cluster, with the condition mentioned above16,17,19,20,33,35
钯集群,有条件above16,17,19,20,33,35
(i.e., an acidic solution or the presence of halides). When contact
（即,酸性溶液或卤化物的存在）.当接触
time between liquid and solid phases is longer, all the reactions
液体和固体的阶段之间的时间越长,所有的反应
occur, adding further H2O2 degradation paths. For intermediate
发生,进一步增加H2O2降解路径.中间的
gas and liquid flow rates, production rate is higher and selectivity
气体和液体的流动速率fl,生产率高和选择性
achieves very interesting values. Gas solubilization in the liquid
实现了非常有趣的值.在液体中溶解气体
phase plays a key role; it can be modified by using solvent that
阶段起着关键的作用；它可以修改fi采用溶剂
selectively increases H2 solubility,34 but also the pressure and
选择性增加H2的溶解度,而且压力和34
the ratio between gas and liquid flow rates can affect the
比之间的气体和液体的流动速率的影响fl
concentration of H2 and O2 in the liquid phase.
在液相中的H2和O2浓度.
These observations allow concluding that operative condition
这些观察可以得出结论认为,操作条件
in the TBR may help in controlling the reaction network, in
在全钢载重子午线可能有助于控制反应网络,在
addition to suitable catalysts, linking the catalyst and the reactor
除了选择合适的催化剂,将催化剂和反应器
design and operation. It has been proved that operative condi-
设计和操作.它已被证明,操作条件—
tions play a major role in driving the reactions toward high
应用于驱动反应向高起主要作用
selectivity for hydrogen peroxide. The results suggest that
用于过氧化氢选择性.结果表明
reactor design and operation may be crucial to improve
反应器的设计和操作可能是至关重要的改善
productivity and selectivity in H2O2 synthesis, together with
在过氧化氢合成的产率和选择性,在一起
developing better catalysts.
开发更好的催化剂