英语翻译
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英语翻译
英语翻译
英语翻译
About Temperature
This document was prepared for the middle school math teachers who are taking part in Project Skymath. It is also hoped that the general public will find it interesting.
Disponible en espanol, toque aqui.
Contents (click on star)
What is Temperature
The Development of Thermometers and Temperature Scales
Heat and Thermodynamics
The Kinetic Theory
Thermal Radiation
3 K - The Temperature of the Universe
Summary
Acknowledgments
References
What is Temperature?
In a qualitative manner, we can describe the temperature of an object as that which determines the sensation of warmth or coldness felt from contact with it.
It is easy to demonstrate that when two objectsof the same material are placed together (physicists say when they are put in thermal contact), the object with the higher temperature cools while the cooler object becomes warmer until a point is reached after which no more change occurs, and to our senses, they feel the same. When the thermal changes have stopped, we say that the two objects (physicists define them more rigorously as systems) are in thermal equilibrium . We can then define the temperature of the system by saying that the temperature is that quantity which is the same for both systems when they are in thermal equilibrium.
If we experiment further with more than two systems, we find that many systems can be brought into thermal equilibrium with each other; thermal equilibrium does not depend on the kind of object used. Put more precisely,
if two systems are separately in thermal equilibrium with a third, then they must also be in thermal equilibrium with each other,
and they all have the same temperature regardless of the kind of systems they are.
The statement in italics, called the zeroth law of thermodynamics may be restated as follows:
If three or more systems are in thermal contact with each other and all in equilibrium together, then any two taken separately are in equilibrium with one another. (quote from T. J. Quinn's monograph Temperature)
Now one of the three systems could be an instrument calibrated to measure the temperature - i.e. a thermometer. When a calibrated thermometer is put in thermal contact with a system and reaches thermal equilibrium, we then have a quantitative measure of the temperature of the system. For example, a mercury-in-glass clinical thermometer is put under the tongue of a patient and allowed to reach thermal equilibrium in the patient's mouth - we then see by how much the silvery mercury has expanded in the stem and read the scale of the thermometer to find the patient's temperature.
What is a Thermometer?
A thermometer is an instrument that measures the temperature of a system in a quantitative way. The easiest way to do this is to find a substance having a property that changes in a regular way with its temperature. The most direct 'regular' way is a linear one:
t(x) = ax + b,
where t is the temperature of the substance and changes as the property x of the substance changes. The constants a and b depend on the substance used and may be evaluated by specifying two temperature points on the scale, such as 32° for the freezing point of water and 212° for its boiling point.
For example, the element mercury is liquid in the temperature range of -38.9° C to 356.7° C (we'll discuss the Celsius ° C scale later). As a liquid, mercury expands as it gets warmer, its expansion rate is linear and can be accurately calibrated.
The mercury-in-glass thermometer illustrated in the above figure contains a bulb filled with mercury that is allowed to expand into a capillary. Its rate of expansion is calibrated on the glass scale.
The Development of Thermometers and Temperature Scales
The historical highlights in the development of thermometers and their scales given here are based on "Temperature" by T. J. Quinn and "Heat" by James M. Cork.
One of the first attempts to make a standard temperature scale occurred about AD 170, when Galen, in his medical writings, proposed a standard "neutral" temperature made up of equal quantities of boiling water and ice; on either side of this temperature were four degrees of heat and four degrees of cold, respectively.
The earliest devices used to measure the temperature were called thermoscopes.
They consisted of a glass bulb having a long tube extending downward into a container of colored water, although Galileo in 1610 is supposed to have used wine. Some of the air in the bulb was expelled before placing it in the liquid, causing the liquid to rise into the tube. As the remaining air in the bulb was heated or cooled, the level of the liquid in the tube would vary reflecting the change in the air temperature. An engraved scale on the tube allowed for a quantitative measure of the fluctuations.
The air in the bulb is referred to as the thermometric medium, i.e. the medium whose property changes with temperature.
In 1641, the first sealed thermometer that used liquid rather than air as the thermometric medium was developed for Ferdinand II, Grand Duke of Tuscany. His thermometer used a sealed alcohol-in-glass device, with 50 "degree" marks on its stem but no "fixed point" was used to zero the scale. These were referred to as "spirit" thermometers.
Robert Hook, Curator of the Royal Society, in 1664 used a red dye in the alcohol . His scale, for which every degree represented an equal increment of volume equivalent to about 1/500 part of the volume of the thermometer liquid, needed only one fixed point. He selected the freezing point of water. By scaling it in this way, Hook showed that a standard scale could be established for thermometers of a variety of sizes. Hook's original thermometer became known as the standard of Gresham College and was used by the Royal Society until 1709. (The first intelligible meteorological records used this scale).
In 1702, the astronomer Ole Roemer of Copenhagen based his scale upon two fixed points: snow (or crushed ice) and the boiling point of water, and he recorded the daily temperatures at Copenhagen in 1708- 1709 with this thermometer.
It was in 1724 that Gabriel Fahrenheit, an instrument maker of Däanzig and Amsterdam, used mercury as the thermometric liquid. Mercury's thermal expansion is large and fairly uniform, it does not adhere to the glass, and it remains a liquid over a wide range of temperatures. Its silvery appearance makes it easy to read.
Fahrenheit described how he calibrated the scale of his mercury thermometer:
"placing the thermometer in a mixture of sal ammoniac or sea salt, ice, and water a point on the scale will be found which is denoted as zero. A second point is obtained if the same mixture is used without salt. Denote this position as 30. A third point, designated as 96, is obtained if the thermometer is placed in the mouth so as to acquire the heat of a healthy man." (D. G. Fahrenheit,Phil. Trans. (London) 33, 78, 1724)
On this scale, Fahrenheit measured the boiling point of water to be 212. Later he adjusted the freezing point of water to 32 so that the interval between the boiling and freezing points of water could be represented by the more rational number 180. Temperatures measured on this scale are designated as degrees Fahrenheit (° F).
In 1745, Carolus Linnaeus of Upsula, Sweden, described a scale in which the freezing point of water was zero, and the boiling point 100, making it a centigrade (one hundred steps) scale. Anders Celsius (1701-1744) used the reverse scale in which 100 represented the freezing point and zero the boiling point of water, still, of course, with 100 degrees between the two defining points.
In 1948 use of the Centigrade scale was dropped in favor of a new scale using degrees Celsius (° C). The Celsius scale is defined by the following two items that will be discussed later in this essay:
(i) The triple point of water is defined to be 0.01° C.
(ii) A degree Celsius equals the same temperature change as a degree on the ideal-gas scale.
On the Celsius scale the boiling point of water at standard atmospheric pressure is 99.975 C in contrast to the 100 degrees defined by the Centigrade scale.
To convert from Celsius to Fahrenheit: multiply by 1.8 and add 32.
° F = 1.8° C + 32
° K = ° C + 273.
(Or, you can get someone else to do it for you!)
In 1780, J. A. C. Charles, a French physician, showed that for the same increase in temperature, all gases exhibited the same increase in volume. Because the expansion coefficient of gases is so very nearly the same, it is possible to establish a temperature scale based on a single fixed point rather than the two fixed- point scales, such as the Fahrenheit and Celsius scales. This brings us back to a thermometer that uses a gas as the thermometric medium.
In a constant volume gas thermometer a large bulb B of gas, hydrogen for example, under a set pressure connects with a mercury-filled "manometer" by means of a tube of very small volume. (The Bulb B is the temperature-sensing portion and should contain almost all of the hydrogen). The level of mercury at C may be adjusted by raising or lowering the mercury reservoir R. The pressure of the hydrogen gas, which is the "x" variable in the linear relation with temperature, is the difference between the levels D and C plus the pressure above D.
P. Chappuis in 1887 conducted extensive studies of gas thermometers with constant pressure or with constant volume using hydrogen, nitrogen, and carbon dioxide as the thermometric medium. Based on his results, the Comité International des Poids et Mesures adopted the constant-volume hydrogen scale based on fixed points at the ice point (0° C) and the steam point (100° C) as the practical scale for international meteorology.
Experiments with gas thermometers have shown that there is very little difference in the temperature scale for different gases. Thus, it is possible to set up a temperature scale that is independent of the thermometric medium if it is a gas at low pressure. In this case, all gases behave like an "Ideal Gas" and have a very simple relation between their pressure, volume, and temperature:
pV= (constant)T.
This temperature is called the thermodynamic temperature and is now accepted as the fundamental measure of temperature. Note that there is a naturally-defined zero on this scale - it is the point at which the pressure of an ideal gas is zero, making the temperature also zero. We will continue a discussion of "absolute zero" in a later section. With this as one point on the scale, only one other fixed point need be defined. In 1933, the International Committee of Weights and Measures adopted this fixed point as the triple point of water , the temperature at which water, ice, and water vapor coexist in equilibrium); its value is set as 273.16. The unit of temperature on this scale is called the kelvin, after Lord Kelvin (William Thompson), 1824-1907, and its symbol is K (no degree symbol used).
To convert from Celsius to Kelvin, add 273.
K = ° C + 273.
Thermodynamic temperature is the fundamental temperature; its unit is the kelvin which is defined as the fraction 1/273.16 of the thermodynamic temperature of the triple point of water.
Sir William Siemens, in 1871, proposed a thermometer whose thermometric medium is a metallic conductor whose resistance changes with temperature. The element platinum does not oxidize at high temperatures and has a relatively uniform change in resistance with temperature over a large range. The Platinum Resistance Thermometer is now widely used as a thermoelectric thermometer and covers the temperature range from about -260° C to 1235° C.
Several temperatures were adopted as Primary reference points so as to define the International Practical Temperature Scale of 1968. The International Temperature Scale of 1990 was adopted by the International Committee of Weights and Measures at its meeting in 1989. Between 0.65K and 5.0K, the temperature is defined in terms of the vapor pressure - temperature relations of the isotopes of helium. Between 3.0K and the triple point of neon (24.5561K) the temperature is defined by means of a helium gas thermometer. Between the triple point of hydrogen (13.8033K) and the freezing point of silver (961.78°K) the temperature is defined by means of platinum resistance thermometers. Above the freezing point of silver the temperature is defined in terms of the Planck radiation law.
T. J. Seebeck, in 1826, discovered that when wires of different metals are fused at one end and heated, a current flows from one to the other. The electromotive force generated can be quantitatively related to the temperature and hence, the system can be used as a thermometer - known as a thermocouple. The thermocouple is used in industry and many different metals are used - platinum and platinum/rhodium, nickel-chromium and nickel-aluminum, for example. The National Institute of Standards and Technology (NIST) maintains databases for standardizing thermometers.
For the measurement of very low temperatures, the magnetic susceptibility of a paramagnetic substance is used as the thermometric physical quantity. For some substances, the magnetic susceptibility varies inversely as the temperature. Crystals such as cerrous magnesium nitrate and chromic potassium alum have been used to measure temperatures down to 0.05 K; these crystals are calibrated in the liquid helium range. This diagram and the last illustration in this text were taken from the Low Temperature Laboratory, Helsinki University of Technology's picture archive. For these very low, and even lower, temperatures, the thermometer is also the mechanism for cooling. Several low-temperature laboratories conduct interesting applied and theoretical research on how to reach the lowest possible temperatures and how work at these temperatures may find application.
Heat and Thermodynamics
Prior to the 19th century, it was believed that the sense of how hot or cold an object felt was determined by how much "heat" it contained. Heat was envisioned as a liquid that flowed from a hotter to a colder object; this weightless fluid was called "caloric", and until the writings of Joseph Black (1728-1799), no distinction was made between heat and temperature. Black distinguished between the quantity (caloric) and the intensity (temperature) of heat.
Benjamin Thomson, Count Rumford, published a paper in 1798 entitled "an Inquiry Concerning the Source of Heat which is Excited by Friction". Rumford had noticed the large amount of heat generated when a cannon was drilled. He doubted that a material substance was flowing into the cannon and concluded "it appears to me to be extremely difficult if not impossible to form any distinct idea of anything capable of being excited and communicated in the manner the heat was excited and communicated in these experiments except motion."
But it was not until J. P. Joule published a definitive paper in 1847 that the the caloric idea was abandoned. Joule conclusively showed that heat was a form of energy. As a result of the experiments of Rumford, Joule, and others, it was demonstrated (explicitly stated by Helmholtz in 1847), that the various forms of energy can be transformed one into another.
When heat is transformed into any other form of energy, or when other forms of energy are transformed into heat, the total amount of energy (heat plus other forms) in the system is constant.
This is the first law of thermodynamics, the conservation of energy. To express it another way: it is in no way possible either by mechanical, thermal, chemical, or other means, to obtain a perpetual motion machine; i.e., one that creates its own energy (except in the fantasy world of Maurits Escher's "Waterfall"!)
A second statement may also be made about how machines operate. A steam engine uses a source of heat to produce work. Is it possible to completely convert the heat energy into work, making it a 100% efficient machine? The answer is to be found in the second law of thermodynamics:
No cyclic machine can convert heat energy wholly into other forms of energy. It is not possible to construct a cyclic machine that does nothing but withdraw heat energy and convert it into mechanical energy.
The second law of thermodynamics implies the irreversibility of certain processes - that of converting all heat into mechanical energy, although it is possible to have a cyclic machine that does nothing but convert mechanical energy into heat!
Sadi Carnot (1796-1832) conducted theoretical studies of the efficiencies of heat engines (a machine which converts some of its heat into useful work). He was trying to model the most efficient heat engine possible. His theoretical work provided the basis for practical improvements in the steam engine and also laid the foundations of thermodynamics. He described an ideal engine, called the Carnot engine, that is the most efficient way an engine can be constructed. He showed that the efficiency of such an engine is given by
efficiency = 1 - T"/T',
where the temperatures, T' and T" , are the hot and cold "reservoirs" , respectively, between which the machine operates. On this temperature scale, a heat engine whose coldest reservoir is zero degrees would operate with 100% efficiency. This is one definition of absolute zero, and it can be shown to be identical to the absolute zero we discussed previously. The temperature scale is called the absolute, the thermodynamic , or the kelvin scale.
The way that the gas temperature scale and the thermodynamic temperature scale are shown to be identical is based on the microscopic interpretation of temperature, which postulates that the macroscopic measurable quantity called temperature is a result of the random motions of the microscopic particles that make up a system.
The Kinetic Theory
This brief summary is abridged from a more detailed discussion to be found in Quinn's "Temperature"
About the same time that thermodynamics was evolving, James Clerk Maxwell (1831-1879) and Ludwig Boltzmann (1844-1906) developed a theory describing the way molecules moved - molecular dynamics. The molecules that make up a perfect gas move about, colliding with each other like billiard balls and bouncing off the surface of the container holding the gas. The energy associated with motion is called Kinetic Energy and this kinetic approach to the behavior of ideal gases led to an interpretation of the concept of temperature on a microscopic scale.
温度
-------------------------------------------------- -----------
-------------------
什么是温度
发展的温度计和温度秤
热和热力学
动力学理论
热辐射
3 K -温度的宇宙
摘要
致谢
参考资料
什么是温度?
在定性的方式,我们可以描述一个物体的温度所决定的感觉温暖
或冷漠感到从联系.
很容易证明,当两个相同的材料放在一起(物理学家说,当他们
把在接触) ,对象与较高的温度变冷,而凉爽的对象变得温暖,
直到点后达成的,没有更多的变化发生时,和我们的理智,他们
同样的感觉.当热的变化已经停止,我们说,这两个物体(物理
学家更严格地界定他们的系统)的热平衡.然后,我们便可确定
该系统的温度说,温度是数量是相同的系统时,在热平衡.
如果我们的实验进一步有两个以上的系统,我们发现,许多系统
可以使热平衡彼此;热平衡并不取决于种对象使用.提出更确切地
说,
如果两个系统分别在热平衡的三分之一,那么他们也必须在热平
衡彼此,他们都具有相同的温度,无论什么样的制度中都.
声明楷体字,称为零定律热力学可重如下:
如果三个或更多的系统,热相互联系和共同所有的平衡,那么任
何两个单独的平衡彼此. (引自苏灿奎因的专着,温度)
现在是三个系统可以是一个工具校准测量温度-即温度计.当校...
文字超过了10000字,发不了了,不好意思