英语翻译The impedance plot for N80 carbon steel in 3% NaClsolutions in the absence and presence of 2M2 at pH 4 and25°C is illustrated as Nyquist plots in Fig.2.All the EISplots have a depressed semicircle at high frequencies withcenter under the
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英语翻译The impedance plot for N80 carbon steel in 3% NaClsolutions in the absence and presence of 2M2 at pH 4 and25°C is illustrated as Nyquist plots in Fig.2.All the EISplots have a depressed semicircle at high frequencies withcenter under the
英语翻译
The impedance plot for N80 carbon steel in 3% NaCl
solutions in the absence and presence of 2M2 at pH 4 and
25°C is illustrated as Nyquist plots in Fig.2.All the EIS
plots have a depressed semicircle at high frequencies with
center under the real axis,which is the characteristic for
solid electrodes and has been attributed to roughness and
other inhomogeneties of the electrode [32,33].The highfrequency
capacitive loop is attributed to the double layer
capacity in parallel with the charge-transfer resistance (Rct).
Though it is probably a composite value representing
dissolution of the iron and other alloying elements,it is
governed by the dissolution of iron since iron is the major
component of the alloy and iron is a highly active metal in
acidic media [34].
In the absence of the inhibitor (Fig.2 inset),the
impedance spectrum is characterized by a low-frequency
inductive loop.The inductive loop is ascribed to the
adsorption of species exhibiting negative change in the
surface coverage with potential [34,35] on the surface of
the metal.As the 2M2 is added into the system,the
inductive loop is transformed into an oblique line (of about
45°) at the low frequency; a typical feature of Warburg
impedance.The Warburg impedance is an indication of
diffusion control as species transfer through surface film or
mass transport through the electrolyte.A closer look at the
curves also shows an indication of a capacitive loop at low
frequency in the presence of 2M2.
英语翻译The impedance plot for N80 carbon steel in 3% NaClsolutions in the absence and presence of 2M2 at pH 4 and25°C is illustrated as Nyquist plots in Fig.2.All the EISplots have a depressed semicircle at high frequencies withcenter under the
阻抗情节为N80碳素结构钢在3%的盐
解决方案在在场或不在场时的2M2 pH值4
25°C为奈奎斯特在图2.所有的增加
有一个沮丧的半圆在高频段
中心轴,这是真正的特性
固体电极和被归因于粗糙度和
其他inhomogeneties电极(32、33].在高频
电容回路,两层
能力与硝基苯电阻(Rct).
尽管它可能是一个复合价值的代表
解散的铁和其他的合金元素,它是
受撤销铁因为铁是最主要的
组成的合金和铁是高度活跃的金属
酸性媒介[34].
在缺乏的乙酰胆碱酯酶抑制剂(图2)、插图
阻抗频谱特征是低
感应圈.这个感应线圈的
展出的吸附的负面变化的物种
与潜在的表面覆盖度,35][34岁的表面上
金属.作为2M2添加到该系统,
电感线圈转变成一条斜线(约
45°),在一个典型的低频率的特点;糖酵解
阻抗.糖酵解阻抗的一个迹象
作为物种传递通过扩散控制膜或
大众运输通过电解液.仔细看看
曲线的迹象,也展示了一个电容回路在低
在2M2频率.