英语翻译the average length of the dispersed clay particles,andhence the aspect ratio.Fig.81 represents thedependence of the tensile modulus E measured at120 8C for exfoliated N6 nanocomposites with variousclay content,obtained by the in situ inte

英语翻译the average length of the dispersed clay particles,andhence the aspect ratio.Fig.81 represents thedependence of the tensile modulus E measured at120 8C for exfoliated N6 nanocomposites with variousclay content,obtained by the in situ inte
英语翻译
the average length of the dispersed clay particles,and
hence the aspect ratio.Fig.81 represents the
dependence of the tensile modulus E measured at
120 8C for exfoliated N6 nanocomposites with various
clay content,obtained by the in situ intercalative
polymerization of 1-caprolactam in the presence of
protonated aminododecanoic acid-modified MMT
and saponite.Moreover,the difference in the extent
of exfoliation,as observed for N6-based nanocomposites
synthesized by the in situ intercalative polymerization
of 1-caprolactam using Naþ-MMT and
various acids,strongly influenced the final modulus
of the nanocomposites.
Table 14 summarizes the tensile modulus of
1potNCH together with neat N6 and NCH prepared
via in situ intercalative ring-opening polymerization
of 1-caprolactam [135].The excellent modulus in the
case of 1potNCH is attributed to the uniformly
dispersed silicate layers.Furthermore,1potNCH has
improved mechanical properties when compared with
NCH.The polymer matrix in the nanocomposites
prepared by a one pot synthesis is the homopolymer of
N6,whereas in the case of NCH prepared via
intercalative ring-opening polymerization,the matrix
is a copolymer of N6 and a small amount of N12.The
presence of N12 may give rise to the lower modulus.
One can observe variations of the modulus of the
nanocomposites based on the various kinds of
acids used to catalyze the polymerization [135].
The WAXD peak intensity (Im; inversely related to
the exfoliation of clay particles) also depends on the
nature of the acid used to catalyze the polymerization
process.For an increase in the Im values,a parallel
decrease in the modulus is observed,indicating that
exfoliated layers are the main factor responsible for
the stiffness improvement.Intercalated particles,
having a less important aspect ratio,play a minor
role.These observations are further confirmed in
Fig.82,which presents the evolution of the tensile
modulus at room temperature of N6 nanocomposites
obtained by melt extrusion as a function of the filler
content [142]

英语翻译the average length of the dispersed clay particles,andhence the aspect ratio.Fig.81 represents thedependence of the tensile modulus E measured at120 8C for exfoliated N6 nanocomposites with variousclay content,obtained by the in situ inte
看的头大``````
平均长度分散粘土颗粒,
因此,长宽比.图.81名代表
依赖的拉伸模量E测量
120 8C条为脱落N6的纳米复合材料的各种
粘土含量,获得了由在原位插
聚合1 -己内酰胺在驻留
质子氨基酸改性市场失当行为审裁处
和皂石.此外,程度不同而
对剥离,作为观察N6的基纳米复合材料
合成了由在原位插层聚合
1 -己内酰胺使用naþ -市场失当行为审裁处及
各种酸,强烈地影响最后的模
该纳米复合材料.
表14总结了拉伸模量的
1potnch一起整齐N6的准备和nch
通过在原位插开环聚合
1 -己内酰胺[ 135 ] .优良的弹性模量,在
案件1potnch的原因是一致
分散的硅酸盐层.此外,已1potnch
改善力学性能的比较
nch .聚合物基体中纳米复合材料
编写一个一锅法合成是聚物的
N6的,而在案件nch准备通过
插开环聚合,矩阵
是一种共聚物的N6的和少量的n12 .那个
在场的n12 ,可能会引起低弹性模量.
一个可以观察到的变化模的
纳米复合材料的基础上,各种
酸用于催化聚合[ 135 ] .
该waxd峰值强度（林秀贞;成反比关系
该剥离的粘土粒子）也依赖于
性质的使用的酸催化聚合
为增加在即时通讯的价值,一个并行
减少在模是观察,显示
脱落层的主要因素负责
刚度改善.插粒子,
有一个同样重要的长宽比,扮演一个小
的作用.这些观察进一步证实,在
图.82 ,其中介绍了演变的拉伸
模量在室温下的N6的纳米复合材料
获得熔融挤出作为一个功能填料
内容[ 142 ]

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