求翻译追加20不要翻译软件的Naturally, we intended to manipulate the clustering behavior in nc- and sc-CO2 through the entrainer effect, which is known to increase the solubility and reaction rate in sc-CO2 but has never been applied to a p
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求翻译追加20不要翻译软件的Naturally, we intended to manipulate the clustering behavior in nc- and sc-CO2 through the entrainer effect, which is known to increase the solubility and reaction rate in sc-CO2 but has never been applied to a p
求翻译追加20不要翻译软件的
Naturally, we intended to manipulate the clustering behavior in nc- and sc-CO2 through the entrainer effect, which is known to increase the solubility and reaction rate in sc-CO2 but has never been applied to a photochirogenic reaction. However, in this enantiodifferentiating photoaddition to aromatic alkenes, a substantial amount of alcohol (0.5 M) has to be added to effectively capture the radical cationic intermediate formed upon electrontransfer interaction of substrate with chiral sensitizer. This does not allow us to closely examine the pure entrainer effect or to manipulate the product’s ee by entrainer clustering in this photochirogenic system. Given this, we decided to use a “self-complete” photosubstrate that carries a hydroxyl group at the ω-position of 1,1-diphenyl-1-alkene for enabling the intramolecular nucleophilic attack to the olefinic moiety upon interaction with an excited sensitizer.
请把上述文字翻译成英文,不要翻译软件的,追加20!谢谢
要翻译成中文,不要意思,谢谢各位了
求翻译追加20不要翻译软件的Naturally, we intended to manipulate the clustering behavior in nc- and sc-CO2 through the entrainer effect, which is known to increase the solubility and reaction rate in sc-CO2 but has never been applied to a p
当然,我们打算操纵集群行为的数控和超临界CO2通过夹带效应,这是众所周知的增加溶解度和反应速度在超临界CO2 ,但从来没有适用于photochirogenic反应.然而,在这enantiodifferentiating photoaddition对芳香烯烃,大量的酒精（ 0.5米）已被添加到有效捕捉自由基阳离子中间形成的相互作用后electrontransfer底手性增敏剂.这并不使我们能够仔细审查纯夹带影响或操纵该产品的企业版的夹带集群系统在这photochirogenic .鉴于此,我们决定使用“自我完成” photosubstrate带有羟基组在ω -立场1,1 -二苯基- 1 -烯烃,使分子内的亲核攻击时烯基与兴奋敏.