英语翻译Figure 3.IR absorption spectra of SO2 adsorption into Ni(bdc)(ted)0.5 as a function of SO2 initial pressure recorded immediately after evacuation (within 16 s).All spectra are referenced to theactivated (i.e.empty) MOF.Inset shows the low

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英语翻译Figure3.IRabsorptionspectraofSO2adsorptionintoNi(bdc)(ted)0.5asafunctionofSO2initialpressurereco

英语翻译Figure 3.IR absorption spectra of SO2 adsorption into Ni(bdc)(ted)0.5 as a function of SO2 initial pressure recorded immediately after evacuation (within 16 s).All spectra are referenced to theactivated (i.e.empty) MOF.Inset shows the low
英语翻译
Figure 3.IR absorption spectra of SO2 adsorption into Ni(bdc)(ted)0.5 as a function of SO2 initial pressure recorded immediately after evacuation (within 16 s).All spectra are referenced to the
activated (i.e.empty) MOF.Inset shows the low pressure region from bottom to top:600 mtor,1 Torr,2 Torr,3 Torr.The black lines are associated with SO2-related features and the red dash lines with MOF-related features arising from SO2 induced perturbation.
Figure 4 shows the evolution of SO2 in Ni(bdc)(ted)0.5 after a loading at 286 Torr.Upon evacuation at room temperature,the physisorbed species characterized by modes at 1326 cm-1 and 1144 cm-1 gradually desorbs.In contrast,the two bands at 1242 cm-1 and 1105 cm-1 remain relatively strong,indicating that another more strongly bound SO2 species is present in the frameworks.
Figure 4.IR absorption spectra recorded 0.5 min,0.5h and 5h after evacuation at room temperature after loading SO2 at 286 Torr ,and then after at 150 °C for additional 3 h.All spectra are referenced to the activated (i.e.empty) MOF.The vertical black lines are associated with SO2-related features and the red dash or dot lines with MOF-related features arising from SO2-induced perturbations.

英语翻译Figure 3.IR absorption spectra of SO2 adsorption into Ni(bdc)(ted)0.5 as a function of SO2 initial pressure recorded immediately after evacuation (within 16 s).All spectra are referenced to theactivated (i.e.empty) MOF.Inset shows the low
图3, 以SO2 在Ni(bcd)(ted)0.5 中的红外吸收能力作为特征前提下,在刚刚符合真空条件下(的16秒内)测出SO2的压强.所有光谱图像都关联到活性金属有机框架(如果MOF是指metal organic framework,本人不学金属化学不了解这个).附图给了低压强区域(从低到高):600 mtor, 1torr, 2 torr, 3 torr(没见过这个单位,不晓得怎么翻译).黑线是表示SO2的,红线是表示MOF-关联特征由提升SO2引起的微动.
图4 是关于 SO2在 Ni(bdc)(ted)0.5 到了286 Torr 时期的发展图像.在室内温度的环境下,其物理吸附能力体现是在 1326cm^-1 跟 1144cm^-1的形态下呈现逐渐吸收.反之, 在1242cm^-1 跟 1105cm-1的区域上吸附性相对要强, 其表明,还有其他吸附性更强的与SO2结合的物质存在于结构中(不确定frameworks怎么翻译,我学术上的中文词汇量很小).
图4,红外光谱图需要在室内温度真空条件以及SO2到286Torr的情况下 0.5分钟, 0.5小时 和5小时 时测量并记录, 然后再放置到150摄氏度的环境中遇热3小时.所有的光谱都参照活性金属有机框架(用到图3我猜?). 竖着的黑线是SO2特征,红线或虚线表明MOF-关联特征由提升SO2引起的微动.
大概就是这个意思,你是读化学工程的吗?

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