英语翻译X-ray crystallographic analysis revealed the structure ofthe nickel(II) complex (Figure 2).18 The four atoms of thedonor set (N1,N2,S1,S2) and Ni1 essentially lie in a plane.The dihedral angle between the two coordination planes,N1-Ni1-S1

英语翻译X-ray crystallographic analysis revealed the structure ofthe nickel(II) complex (Figure 2).18 The four atoms of thedonor set (N1,N2,S1,S2) and Ni1 essentially lie in a plane.The dihedral angle between the two coordination planes,N1-Ni1-S1
英语翻译
X-ray crystallographic analysis revealed the structure of
the nickel(II) complex (Figure 2).18 The four atoms of the
donor set (N1,N2,S1,S2) and Ni1 essentially lie in a plane.
The dihedral angle between the two coordination planes,N1-Ni1-S1 and N2-Ni1-S2,is 7.96(9)°,indicating slight
distortion toward tetrahedral geometry from the square planar
structure.It is noteworthy that the coordination bonds of one
thiosalicylidene moiety (Ni1-S2,2.1973(7) Å; Ni1-N2,
1.9462(19) Å) are considerably longer than those of the other
(Ni1-S1,2.1399(6) Å; Ni1-N1,1.897(2) Å) (Table 1).The
differences (0.057 Å for Ni-S and 0.049 Å for Ni-N) are
much larger than those of the known nickel(II) complexes
of thiosalicylidenediamine N2S2 ligands (less than 0.035 Å
for Ni-S and 0.014 Å for Ni-N).9,10,19-22 The dihedral angle between the coordination plane (defined
as the least-squares plane of Ni1,N1,N2,S1,and S2) and
the benzene ring B (56.7°) is considerably larger than that
for the benzene ring A (14.6°).Thus,the molecule is bent
at the S2-N2 line.The elongation of the coordination bonds,
Ni1-S2 and Ni1-N2,indicates weaker interaction of the
ligand with the nickel center,22 probably due to the distorted
geometry of the complex.

英语翻译X-ray crystallographic analysis revealed the structure ofthe nickel(II) complex (Figure 2).18 The four atoms of thedonor set (N1,N2,S1,S2) and Ni1 essentially lie in a plane.The dihedral angle between the two coordination planes,N1-Ni1-S1
X 光晶体学的分析向暴露镍(II）综合体(计算2）四原子赠送人的按设定 .18的(N1,N2,S1,S2）的结构和 Ni1 主要位于在一架飞机中.在两协调飞机,N1-Ni1-S1 和 N2-Ni1-S2 之间的二面角是7.96(9)°,朝着从方形平面的结构的四面体的几何学的指示轻微变形.它是一 thiosalicylidene 一半的值得注意那协调粘合到一起 Ni1-S2,2.1973(7)Å； Ni1-N2,1.9462(19)Å是与其他的那些相比相当大更长 Ni1-S1,2.1399(6)Å；Ni1-N1,1.897(2)Å（;桌子1）.之间的差异0.057Å；为 Ni S 和0.049Å；因为 Ni N 是与 thiosalicylidenediamine N2S2 配体的以而闻名镍(II）综合体的那些相比大得多的更少一点与相比0.035Å；为 Ni S 和0.014Å；为 Ni N.9,10,19-22在,把协调飞机（定义为 Ni1,N1,N2,S1 和 S2）中最最小二乘法飞机和苯环 B(56.7°）之间的二面角为苯环 A(14.6°）是与那个相比相当大更大.因此,分子被在 S2-N2 线方面弯曲.协调债券 ,Ni1-S2 和 Ni1-N2 的拉长大概由于综合体的扭曲几何学指示配体的有镍 center,22 的更弱相互作用.

X光晶体学的分析向暴露镍(II）综合体(计算2）四原子赠送人的按设定 .18的(N1,N2,S1,S2）的结构和 Ni1 主要位于在一架飞机中。在两协调飞机,N1-Ni1-S1 和 N2-Ni1-S2 之间的二面角是7.96(9)°,朝着从方形平面的结构的四面体的几何学的指示轻微变形。它是一 thiosalicylidene 一半的值得注意那协调粘合到一起 Ni1-S2,2.1973(7)&Ari...

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X光晶体学的分析向暴露镍(II）综合体(计算2）四原子赠送人的按设定 .18的(N1,N2,S1,S2）的结构和 Ni1 主要位于在一架飞机中。在两协调飞机,N1-Ni1-S1 和 N2-Ni1-S2 之间的二面角是7.96(9)°,朝着从方形平面的结构的四面体的几何学的指示轻微变形。它是一 thiosalicylidene 一半的值得注意那协调粘合到一起 Ni1-S2,2.1973(7)Å； Ni1-N2,1.9462(19)Å是与其他的那些相比相当大更长 Ni1-S1,2.1399(6)Å；Ni1-N1,1.897(2)Å（;桌子1）。之间的差异0.057Å；为 Ni S 和0.049Å；因为 Ni N 是与 thiosalicylidenediamine N2S2 配体的以而闻名镍(II）综合体的那些相比大得多的更少一点与相比0.035Å；为 Ni S 和0.014Å；为 Ni N.9,10,19-22在，把协调飞机（定义为 Ni1,N1,N2,S1 和 S2）中最最小二乘法飞机和苯环 B(56.7°）之间的二面角为苯环 A(14.6°）是与那个相比相当大更大。因此，分子被在 S2-N2 线方面弯曲。协调债券 ,Ni1-S2 和
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