英语翻译Removal of NO,and SO2 from Flue Gas by Peracid Solutions小标题:David Littlejohn and S.G.Chang* Lawrence Berkeley Laboratory,University of California,Berkeley,California 94720Treatment of water-soluble carboxylic acids with concentrat

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英语翻译RemovalofNO,andSO2fromFlueGasbyPeracidSolutions小标题:DavidLittlejohnandS.G.Chang*LawrenceBerkeleyL

英语翻译Removal of NO,and SO2 from Flue Gas by Peracid Solutions小标题:David Littlejohn and S.G.Chang* Lawrence Berkeley Laboratory,University of California,Berkeley,California 94720Treatment of water-soluble carboxylic acids with concentrat
英语翻译
Removal of NO,and SO2 from Flue Gas by Peracid Solutions
小标题:David Littlejohn and S.G.Chang*
Lawrence Berkeley Laboratory,University of California,Berkeley,California 94720
Treatment of water-soluble carboxylic acids with concentrated hydrogen peroxide generates solutions of peracids.These compounds can rapidly oxidize NO,and SO2 to their respective oxyanions,making them useful in flue gas treatment.The properties of performic acid,peracetic acid,and perpropionic acid are reported and are compared with peroxymonosulfuric acid.The chemistry of NO,and SO2 removal by these compounds is discussed.
正文:
Aqueous solutions of a number of oxidizing compounds have been studied to determine their effectiveness in re- moving NO,and SOz from flue gas (Kobayashi et al.,1977).A wet process exists using hydrogen peroxide to remove NO,and SOz from flue gas,but it is only effective under very acidic conditions (Cooper,1984).The process de- veloped by Cooper requires an acidic medium because hydrogen peroxide is a much more effective oxidizing agent in the form of H302+,which exists in acidic conditions (Purcell and Kotz,1977).The process needs an alkaline wash of the treated gas to remove volatilized nitrogen oxides from the acidic peroxide solution.We have made further studies of oxidizing compounds to determine their usefulness in flue gas clean-up systems.One class of compounds that has been found to be effective in NO,and SOp removal is that of peroxyacids,or peracids.Peracids have been found to function over a much wider pH range than hydrogen peroxide alone.They are formed by a reaction of hydrogen peroxide and some compounds con- taining a carboxylic acid group.Performic acid (PFA),peracetic acid (PAA),and perpropionic acid (PPA) were studied and compared with peroxymonosulfuric acid (PMSA),also known as Caro's acid.
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英语翻译Removal of NO,and SO2 from Flue Gas by Peracid Solutions小标题:David Littlejohn and S.G.Chang* Lawrence Berkeley Laboratory,University of California,Berkeley,California 94720Treatment of water-soluble carboxylic acids with concentrat
题目二氧化硫脱除氮氧化物、从烟气通过光的解决方案
小标题:大卫Littlejohn和s .g .长安
劳伦斯伯克利实验室,美国加州大学柏克莱分校94720加州
治疗的水溶性羧酸与集中过氧化氢的peracids收敛.这些化合物能够迅速、二氧化硫氧化没有给他们,使他们各自的oxyanions有用的烟气治理.performic的性质、酸、过氧乙酸perpropionic酸,较之peroxymonosulfuric报道.化学和二氧化硫,这些化合物进行了探讨.
正文:水溶液的氧化化合物的研究来确定其有效性重新移动,但他从没有烟气(小林等,1977年).湿过程中存在的过氧化氢,并注意移除一个从烟气,但这仅仅是有效的在酸性环境下(库珀,1984年).德- veloped中酸性介质由库珀要求因为过氧化氢是一种更有效的氧化剂的形式而存在H302 +,在酸性环境下(Purcell和Kotz,1977年).这个过程需要治疗的碱性洗除去volatilized氮氧化物气体从酸性过氧化的解决方案.我们已经作了进一步的研究来确定其有效性氧化化合物在烟气净化系统.有一种化合物,它被认为是有效的在没有,是peroxyacids SOp切除,或peracids.Peracids已经发现功能到更广的pH范围比过氧化氢.它们是由一个反应的过氧化氢和一些反对-泰宁一个羧酸集团.Performic酸(PFA)、过氧乙酸、perpropionic(聚酸(PPA)进行了研究,并与peroxymonosulfuric酸(PMSA),也称为开罗的酸.

题目:NO的清除,从烟气SO2的过氧酸解
小标题:大卫利特尔约翰和昂张*
劳伦斯伯克利实验室,加州大学伯克利分校,加州94720
与过氧化氢浓缩水溶性羧酸处理生成peracids解决方案。这些化合物可以迅速氧化一氧化氮,二氧化硫和各自oxyanions,使他们在烟气治疗作用。该performic酸,过氧乙酸属性和perpropionic酸的报告,并与peroxymon...

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题目:NO的清除,从烟气SO2的过氧酸解
小标题:大卫利特尔约翰和昂张*
劳伦斯伯克利实验室,加州大学伯克利分校,加州94720
与过氧化氢浓缩水溶性羧酸处理生成peracids解决方案。这些化合物可以迅速氧化一氧化氮,二氧化硫和各自oxyanions,使他们在烟气治疗作用。该performic酸,过氧乙酸属性和perpropionic酸的报告,并与peroxymonosulfuric酸比较。 NO的化学,以及这些化合物的脱硫进行了讨论。
正文:
一氧化化合物数量水溶液进行了研究,以确定其在重新移动无影响,从烟道气体(小林等人苏兹。,1977)。使用过程中存在的湿式过氧化氢清除一氧化氮,并苏兹从烟气,但它只有在酸性条件下非常有效(库珀1984年)。这个过程去定科目由库珀要求的酸性媒介,因为过氧化氢是一种更为有效的氧化中的H302 +,这在(裴熙亮和科茨,1977年)酸性条件下存在的形式代理。这个过程需要一个经处理后的气体挥发碱性清洗,以消除从酸性双氧水氮氧化物。我们已取得的氧化化合物进一步研究,以确定它们的用处在烟气清洁系统。一类是已经被发现在没有有效的化合物,和SOP搬迁是,过氧酸,或peracids。 Peracids已发现功能在更大的范围内pH值比单独过氧化氢。他们是由一个过氧化氢和一些化合物CON组,泰宁羧酸基团反应。 Performic酸(煤灰),过氧酸(PAA)和perpropionic酸(苯丙醇胺)进行了研究,并与peroxymonosulfuric酸(PMSA),也称为卡罗的酸著名。

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