英语翻译利用邻苯二胺席夫碱分别与乙酸锌、乙酸铜、乙酸锰、氯化钴合成了四种邻苯二胺席夫碱金属配合物,采用紫外和红外光谱对其结构进行了表征.以合成的邻苯二胺席夫碱金属配合物

英语翻译利用邻苯二胺席夫碱分别与乙酸锌、乙酸铜、乙酸锰、氯化钴合成了四种邻苯二胺席夫碱金属配合物,采用紫外和红外光谱对其结构进行了表征.以合成的邻苯二胺席夫碱金属配合物
英语翻译
利用邻苯二胺席夫碱分别与乙酸锌、乙酸铜、乙酸锰、氯化钴合成了四种邻苯二胺席夫碱金属配合物,采用紫外和红外光谱对其结构进行了表征.以合成的邻苯二胺席夫碱金属配合物为催化剂催化氧化松香,测定了氧化产物的转化率和软化点.并采用正交实验,优化了氧化的工艺条件.实验结果表明,邻苯二胺席夫碱锰、钴、铜和锌金属配合物催化氧化松香的转化率分别为：77.08%,72.92%,70.67%,63.25%,而相对的软化点分别为：97.1、94.0、98.9、96.8℃；氧化反应的各因素的重要性次序为:反应温度>H2O2的用量>催化剂用量>反应时间.在催化剂用量为0.2%（质量比,对松香）,反应温度70℃,30% H2O2用量为20mL,反应时间为3h的最佳条件下,转化率为73.9%.红外、紫外、高效液相色谱和质谱测试表明,松香在邻苯二胺席夫碱金属配合物的催化下,氧化生成了含羟基、环氧基、过氧基等官能团的氧化产物.

英语翻译利用邻苯二胺席夫碱分别与乙酸锌、乙酸铜、乙酸锰、氯化钴合成了四种邻苯二胺席夫碱金属配合物,采用紫外和红外光谱对其结构进行了表征.以合成的邻苯二胺席夫碱金属配合物
I use one husband alkali benzene p and B respectively Suanxin,ethanoic acid copper,ethanoic acid manganese,cobalt chlorination four adjacent synthetic benzene p seats husband alkali metal with objects,the use of ultraviolet and infrared spectral structure of its presentation.Synthetic benzene p seats adjacent to the husband with alkali metal catalyst materials for catalytic oxidation rosin,measured by the product of the conversion rate and oxide soften.And the use of orthogonal experiments optimized oxidation process.Experimental results show that benzene p neighbouring seats husband alkali manganese,cobalt,copper and zinc metals from catalytic oxidation rosin with the conversion rate are :77.08%,72.92%,70.67%,63.25% corresponding soften points are :97.1,94.0,98.9,96.8 degrees; Oxidation reactions of the importance of various factors in order :reaction temperature,"H2O2 usage" catalyst consumption,"response time.In a catalyst consumption 0.2 (quality than the rosin),the reaction temperature of 70 degrees,30% H2O2 consumption for 20mL,3h response time for the best conditions,the conversion rate 73.9%.Infrared,ultraviolet,and mass spectrometry Gaoxiaoyexiang tests showed that benzene p rosin in neighbouring seats husband alkali metal objects with catalytic,the oxide containing hydroxy generated,ethylene,or a functional group,such as the Food oxide product.

Make use of the benzene of 邻 two 胺 a man alkali differences synthesized with acetic acid zinc, acetic acid copper, acetic acid manganese, chlorination cobalt four kinds of 邻s benzene two 胺 a man alkal...

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Make use of the benzene of 邻 two 胺 a man alkali differences synthesized with acetic acid zinc, acetic acid copper, acetic acid manganese, chlorination cobalt four kinds of 邻s benzene two 胺 a man alkali metalses match with the thing, adopting the purple outside with the red and outside spectrum as to it's construction proceeded token.Then the benzene of 邻 that synthesize two 胺 a man alkali metals match thing for the catalyst catalyst oxidizes pine the joss-stick, measuresing to oxidize the conversion rate of the outcome with soften to order.Combine adoption is handing over the experiment, excellent turned the craft term that oxidize.Experiment the result expresses, the benzene of 邻 two 胺 a man alkali manganese, cobalt, coppers match with with zinc metals the thing catalyst oxidizes the fragrant conversion in pine rate respectively is:77.08%,72.92%,70.67%,63.25%, but soften to order difference as oppositely:97.1,94.0,98.9 and 96.8 ℃ ;Importance order of sequence that oxidize each factor of the reaction as: Respond the temperature the > H2O2 dosage> the catalyst dosage> respond time.Is 0.2%( the quantity compares, to pine joss-stick) in the catalyst dosage, respond the temperature 70 ℃ ,30% H2O2 dosage is a the best term for, responding time as 3 hs next, the conversion rate is 73.9%.Red outside, purple outside, efficiently liquid mutually the color 谱 expresses with the quality 谱 test, the joss-stick of pine is in the benzene of 邻 two 胺 a man alkali metalses match with the catalyst of the thing next, oxidize born contain the 羟基 , wreath oxygen 基 and wait over the oxygen 基 the organic functions regiment oxidize the outcome.

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