英语翻译These findings prompted us to examine the effects of supercritical carbon dioxide (critical point:31 C,7.38 MPa) as a dynamically fluctuating reaction medium on the photosensitized enantiodifferentiating geometrical isomerization
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英语翻译These findings prompted us to examine the effects of supercritical carbon dioxide (critical point:31 C,7.38 MPa) as a dynamically fluctuating reaction medium on the photosensitized enantiodifferentiating geometrical isomerization
英语翻译
These findings prompted us to examine the effects of supercritical carbon dioxide (critical point:31 C,7.38 MPa) as a dynamically fluctuating reaction medium on the photosensitized enantiodifferentiating geometrical isomerization of cyclooctene and polar addition of alcohols to 1,1-diphenyl-1-alkenes from the entropic point of view.Interestingly,the enantiodifferentiating photoaddition of alcohol to aromatic alkenes shows a sudden leap in product enantiomeric excess (ee) in a narrow pressure range transferring from near-critical to supercritical state,indicating a significant difference in clustering mechanism and/or cluster structure between near-critical and supercritical carbon dioxide (nc- and sc-CO2) and also the vital role of clustering in determining the product’s ee.
翻译成中文,不要翻译软件的,
英语翻译These findings prompted us to examine the effects of supercritical carbon dioxide (critical point:31 C,7.38 MPa) as a dynamically fluctuating reaction medium on the photosensitized enantiodifferentiating geometrical isomerization
这些发现促使我们检验二氧化碳作为从熵的观点使其具有光敏对映差异的几何异构环辛烯和使乙醇极性添加于联苯烯烃动态反应介质临界点的影响.
有趣的是,乙醇添加到芳香烃的对映差异光加成反应表现出剩余的对映结构体在一个狭窄的压强范围内从接近临界点到超临界点的突然跳跃,这标志了二氧化碳在接近临界点和超临界点之间聚类机制和团类结构的重要不同以及聚类在决定产品的剩余时扮演了重要角色.